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Selective Catalytic Reduction
(SCR)
| Selective Catalytic Reduction (SCR)
is the most effective method of controlling
nitrogen oxide emissions (NOx) from combustion
sources. It is a commercially proven flue gas
treatment technology that has been demonstrated to
remove over 90 percent of the NOx contained in
combustion or process exhaust gas. |
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 | Elimination of NOx
creates a healthier environment and meets stringent new
EPA and EU reduction requirements. SCR technology is
widely used on different types of combustion systems
such as coal fired boilers, simple and combined cycle
gas turbines, process boilers, hydrogen reformers, etc.
Virtually any hot flue gas containing NOx can be treated
effectively with the SCR process as a retrofit or as new
equipment.
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The catalyst is at the heart of the
SCR process. It creates a surface for reacting the
NOx and ammonia, and allows for the reaction to
occur within typical flue gas temperature ranges.
The active ingredient in most NOx catalyst is
Vanadium Pentoxide (V2O5) of
various concentrations. For higher temperatures
zeolites, tungsten or titanium matrices may be
utilized as well. Catalyst configurations can be
homogenous honeycomb, coated honeycomb or plate
type catalyst. | The catalyst
opening, composition and volume of catalyst are
determined by components of flue gas chemistry,
treatment temperature and amount of flue gas to be
treated.
| The Ammonia reducing agent is
injected upstream of the catalyst. It is crucial
that ammonia be evenly distributed along the face
of the catalyst. Usually, it is necessary to
ensure that the flue gas flow is even with flow
chevrons and mixing devices. Then, an Ammonia
Injection Grid is used to ensure that the ammonia
is evenly distributed across the flue gas. As an
alternative, urea solutions can be used as a
source of ammonia - converted to ammonia either externally or
in-situ. |
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The reaction occurs in the pores of
the catalyst bank. The catalyst bank may consist
of one or more layers of catalyst for treatment.
On the surface of the catalyst, the NOx will be
selectively reduced by reacting with ammonia
in the presence of oxygen to form harmless
byproducts, water and nitrogen (H2O
&
N2). |
Typically
the range of temperature for this reaction is 500-850°F
(260-454°C). In clean gas applications, specialty
high-temperature formulations are able to achieve high
NOx reduction at temperatures as high as 1100°F (593°C).
This wide temperature range allows for flexibility in a
retrofit situation and choices for multi-pollutant
optimization in new equipment.
Selective
Catalytic Reduction may be used in any industry with
effluent gas at sufficient temperature containing
nitrogen oxides such as Power, Petrochemical, Steel,
Metal production, Pulp and Paper, Cement, Waste to
Energy, Glass, Nitrous Acid Production etc. It is ideal
to meet the EPA's stringent requirements for NOx
reduction in any combustion
application.
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